1) Comparison of Cobalt and Nickel Complexes with Sterically Demanding Cyclic Diphosphine Ligands: Electrocatalytic H2 Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2† (Organometallics) Wednesday September 1st 2010 2) Ligand Variations in New Sulfonamide-Supported Group 4 Ring-Opening Polymerization Catalysts (Organometallics) Wednesday September 1st 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 3) Single-Step Synthesis of Secondary Phosphine Oxides (Organometallics) Wednesday September 1st 2010 4) Copper(I)-Mediated Synthesis of Ferrocenyl Alkyl Ethers† (Organometallics) Wednesday September 1st 2010 5) Reactivity of Tuck-in and Tuck-over Uranium Metallocene Complexes (Organometallics) Wednesday September 1st 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 6) R3E+ Carborane Salts of the Heavier Group 14 Elements: E = Ge, Sn, and Pb (Organometallics) Tuesday August 31st 2010 7) Fragmentation of an N-Substituted One-Coordinate Phosphorus (Phosphaalkyne): Plausible Generation of Monovalent Phosphorus Species† (Organometallics) Tuesday August 31st 2010 8) Tripodal N-Heterocyclic Carbene Complexes of Palladium and Copper: Syntheses, Characterization, and Catalytic Activity (Organometallics) Tuesday August 31st 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 9) Synthesis of Anionic Iron(II) Complex Bearing an N-Heterocyclic Carbene Ligand and Its Catalysis for Aryl Grignard Cross-Coupling of Alkyl Halides (Organometallics) Friday August 27th 2010 10) Deprotonation versus Nucleophilic Substitution in Some Platinum(II) Coordinated Olefins Containing an Electron Withdrawing Group (Organometallics) Friday August 27th 2010 11) Conversion of an Acetylide−Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination (Organometallics) Friday August 27th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 12) Switchable Chromium(II) Complexes of a Chelating Amidophosphine (N−P) for Selective and Nonselective Ethylene Oligomerization (Organometallics) Friday August 27th 2010 13) Rotating Benzyl Substituent in ansa-Bis(indenyl)zirconocenes Controls Propene Polymerization (Organometallics) Friday August 27th 2010 14) Formation of Three New Base Adducts in the Reaction of the Aluminopolysiloxane [Ph2SiO]8[AlO(OH)]4·4Et2O with Propane-1,3-diamine§ (Organometallics) Thursday August 26th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 15) Palladium(II)-Catalyzed Ortho Arylation of 2-Phenoxypyridines with Potassium Aryltrifluoroborates via C−H Functionalization (Organometallics) Thursday August 26th 2010 16) Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition (Organometallics) Thursday August 26th 2010 17) Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes with N-Phenylperimidine-Based Carbene Ligands (Organometallics) Thursday August 26th 2010 0 comments, related, 2 Up Votes 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 18) Acidity of Benzoic Acids Bearing the (CO)5Cr═CN(CH3)2 Group (Organometallics) Thursday August 26th 2010 19) Switched Stereocontrol in Grubbs−Hoveyda Complex Catalyzed ROMP Utilizing Proton-Switched NHC Ligands† (Organometallics) Thursday August 26th 2010 20) Reactivity of Aryldimesitylboranes under Suzuki−Miyaura Coupling Conditions (Organometallics) Thursday August 26th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 21) Low-Temperature Rhodium-Catalyzed Dehydration of Primary Alcohols Promoted by Tetralkylammonium and Imidazolium Halides (Organometallics) Thursday August 26th 2010 22) Two-Way Street Transformation of Boronium and Borane Complexes Facilitated by Amino-Linked N-Heterocyclic Carbene (Organometallics) Thursday August 26th 2010 23) Ligand Electronic Effect on Reductive Elimination of Biphenyl from cis-[Pt(Ph)2(diphosphine)] Complexes Bearing Electron-Poor Diphosphine: Correlation Study between Experimental and Theoretical Results (Organometallics) Wednesday August 25th 2010 0 comments, related, 2 Up Votes 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 24) Five-Coordinate Hydrido−Ruthenium(II) Complexes Featuring N-Heterocyclic Silylene and Carbene Ligands (Organometallics) Wednesday August 25th 2010 25) Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-(S,CNHC) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag4I4(S,CNHC)2 Planar Cluster† (Organometallics) Wednesday August 25th 2010 26) closo-o-Carboranylmethylamine−Pyridine Associations: Synthesis, Characterization, and First Complexation Studies (Organometallics) Wednesday August 25th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 27) Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex (Organometallics) Wednesday August 25th 2010 28) Highly Efficient Reduction of Sulfoxides with the System Borane/Oxo-rhenium Complexes† (Organometallics) Tuesday August 24th 2010 29) Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand (Organometallics) Tuesday August 24th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 30) Preparation of the Alkyl Complex Ta(═NSiMe3)[N(SiMe3)2](CH2But)2. Preferential Oxygen Insertion in Its Reaction with O2 and a Ligand Exchange in the Alkoxide Ta(═NSiMe3)[N(SiMe3)2](OCH2But)2† (Organometallics) Friday August 20th 2010 31) Pyridine-2,6-bis(thioether) (SNS) Complexes of Ruthenium as Catalysts for Transfer Hydrogenation (Organometallics) Friday August 20th 2010 32) Diorganostannide Dianions (R2Sn2−) as Reaction Intermediates Revisited: In Situ 119Sn NMR Studies in Liquid Ammonia (Organometallics) Friday August 20th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 33) Formation of Acylsilenolates from Bis(acyl)trisilanes as the Silicon Analogues of Acylenolates (Organometallics) Friday August 20th 2010 34) Reactions of Bis(tri-tert-butylphosphine)platinum with Metal Hydride Complexes. The Reactions of Pt(P-t-Bu3)2 with HRe(CO)4SbPh3 (Organometallics) Thursday August 19th 2010 35) Catalytic Tail-to-Tail Selective Dimerization of Methyl Methacrylate Promoted by a Ruthenium(0) Complex (Organometallics) Thursday August 19th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 2 Up Votes 36) UV-Photoelectron Spectroscopic Studies on 2-Arylethynyl-1,3,2-benzodiazaboroles† (Organometallics) Wednesday August 18th 2010 37) Synthesis and Structural Features of Boratabenzene Rare-Earth Metal Alkyl Complexes (Organometallics) Wednesday August 18th 2010 38) Cationic Planar Chiral (η6-Arene)Mn(CO)3+ Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+ Complexes (Organometallics) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 39) Monoborane NHC Adducts in the Coordination Sphere of Transition Metals (Organometallics) Wednesday August 18th 2010 40) Efficient Cycloisomerization of Propargyl Amides by Electrophilic Gold(I) Complexes of KITPHOS Monophosphines: A Comparative Study (Organometallics) Wednesday August 18th 2010 41) Why Are (NN2)Ni Pincer Complexes Active for Alkyl−Alkyl Coupling: β-H Elimination Is Kinetically Accessible but Thermodynamically Uphill (Organometallics) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 42) Unexpected Ccarbene−X (X: I, Br, Cl) Reductive Elimination from N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions (Organometallics) Tuesday August 17th 2010 43) Influence of the Ti−O−C Angle on the Oxygen-to-Titanium π-Donation in [Cp2*Ti(III)OR] Complexes∥ (Organometallics) Saturday August 14th 2010 44) Structure and Reactivity of Neutral and Cationic trans-N,N′-Dibenzylcyclam Zirconium Alkyl Complexes (Organometallics) Saturday August 14th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 45) Syntheses and Characterization of Ruthenium Complexes Containing a Doubly Linked Dicyclopentadienyl Ligand and Acetonitrile Ligands (Organometallics) Saturday August 14th 2010 46) Reactions of an Aluminum Amide with Aromatic Nitriles: Formation of Al−N−C Frameworks (Organometallics) Friday August 13th 2010 47) Anion Recognition by Highly Sterically Encumbered 1,2-Diborylferrocenes§ (Organometallics) Friday August 13th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 48) 2-Thia-1,3,5-triaza-7-phosphaadamantane-2,2-dioxide Revisited: Computational and Experimental Studies of a Neglected Phosphine (Organometallics) Friday August 13th 2010 49) Reactions of a Bis-silylene (LSi−SiL, L = PhC(NtBu)2) and a Heteroleptic Chloro Silylene (LSiCl) with Benzil: Formation of Bis(siladioxolene) and Monosiladioxolene Analogue with Five-Coordinate Silicon Atoms in Both Ring Systems (Organometallics) Friday August 13th 2010 50) Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework† (Organometallics) Thursday August 12th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 51) Stereoselective Ring-Opening Polymerization of rac-Lactides Catalyzed by Chiral and Achiral Aluminum Half-Salen Complexes† (Organometallics) Thursday August 12th 2010 52) Synthesis of Ruthenium Boryl Analogues of the Shvo Metal−Ligand Bifunctional Catalyst (Organometallics) Thursday August 12th 2010 53) Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes (Organometallics) Thursday August 12th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 54) Reactivity of Dihydrides MH2P4 (M = Fe, Ru, Os) with SnCl2: Preparation of Bis(trihydridestannyl) Derivatives (Organometallics) Wednesday August 11th 2010 55) Sila- and Germametallacycles of Late Transition Metals† (Organometallics) Wednesday August 11th 2010 56) Reactions of (Et2NCH2CH2NEt2)·H2SiCl2 with Selected Diorganometallic Reagents of Magnesium and Lithium† (Organometallics) Wednesday August 11th 2010 0 comments, related, 1 Up Vote 0 comments, related, 3 Up Votes 0 comments, related, 1 Up Vote 57) Synthesis and Reactivity of Rhodium Mono- and Bis(diolefin) Complexes. Characterization of Intermediates in the Rhodium-Catalyzed Cyclotetramerization of Butadiene† (Organometallics) Wednesday August 11th 2010 58) Cyclometalated Platinum(II) Complexes of Lepidine-Based Ligands as Highly Efficient Electrophosphors (Organometallics) Wednesday August 11th 2010 59) Facile Synthesis of Bifunctional Ligands using LiCH2PPh2═NPh Obtained from [PhNH−PPh3+][Br−] (Organometallics) Wednesday August 11th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 2 Up Votes 60) A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene) (Organometallics) Wednesday August 11th 2010 61) Synthesis and Reactivity of NiII(Phpy)2 (Phpy = 2-Phenylpyridine)† (Organometallics) Tuesday August 10th 2010 62) The First Linear, Homoleptic Triple-Decker Sandwich Complex of an f-Element: A Molecular Model for Organolanthanide Nanowires† (Organometallics) Tuesday August 10th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 63) Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization (Organometallics) Tuesday August 10th 2010 64) Influence of Ring Methylation in Group 15 Tetramethylcyclopentadienyl Complexes, M(C5Me4H)nI3−n (M = As, Sb)† (Organometallics) Tuesday August 10th 2010 65) Electrospray Mass Spectrometric Studies of Two Palladium−Allyl Complexes of the Trost Standard Ligand (Organometallics) Tuesday August 10th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 66) Efficient Heck Reactions Catalyzed by Palladium(0) and -(II) Complexes Bearing N-Heterocyclic Carbene and Amide Functionalities (Organometallics) Tuesday August 10th 2010 67) Platinum(II) and Platinum(IV) Porphyrin Pincer Complexes: Synthesis, Structures, and Reactivity (Organometallics) Tuesday August 10th 2010 68) Heteroselective Polymerization of rac-Lactide in the Presence of Dialkylgallium Alkoxides: The Effect of Lewis Base on Polymerization Stereoselectivity (Organometallics) Saturday August 7th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 69) Flattening a Puckered Pentasilacyclopentadienide Ring by Suppression of the Pseudo Jahn−Teller Effect (Organometallics) Saturday August 7th 2010 70) Synthesis and Structures of Fused N-Heterocylic Carbenes and Their Rhodium Complexes (Organometallics) Friday August 6th 2010 71) Ruthenium, Rhodium, and Iridium Bis(σ-B−H) Diisopropylaminoborane Complexes† (Organometallics) Friday August 6th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 72) Evidence for C−H···X−Ir (X = Cl or I) Hydrogen Bonding between Imidazolium Salts and Iridium-Bound Halides and Formation of Ir(I) NHC Complexes† (Organometallics) Thursday August 5th 2010 73) Reactivity of ortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process† (Organometallics) Thursday August 5th 2010 74) Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes† (Organometallics) Thursday August 5th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 75) Synthesis of cis- and trans-Diisothiocyanato−Bis(NHC) Complexes of Nickel(II) and Applications in the Kumada−Corriu Reaction (Organometallics) Wednesday August 4th 2010 76) Bis(allenylidene) Complexes of Palladium and Platinum† (Organometallics) Wednesday August 4th 2010 77) Electronic Factors Affecting Metal−Metal Interactions in Early/Late Heterobimetallics: Substituent Effects in Zirconium/Platinum Bis(phosphinoamide) Complexes† (Organometallics) Wednesday August 4th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 78) Synthesis of Racemic Aminoalkylferrocenyldichlorophosphanes and -dialkylphosphonites and Their Conversion to Primary Phosphanes† (Organometallics) Wednesday August 4th 2010 79) Triphenylphosphane-Modified Cobalt Catalysts for the Selective Carbonylation of Ethyl Diazoacetate (Organometallics) Wednesday August 4th 2010 80) Developing a Reliable Synthetic Route to cis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems (Organometallics) Wednesday August 4th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 81) The Bridging Acetylene to Bridging Vinylidene Rearrangement in a Triruthenium Carbonyl Cluster: A DFT Mechanistic Study (Organometallics) Wednesday August 4th 2010 82) Arene−Ruthenium(II) Complexes Containing Amino−Phosphine Ligands as Catalysts for Nitrile Hydration Reactions (Organometallics) Wednesday August 4th 2010 83) Bis(pyridyl)siloxane Oligomeric Ligands for Palladium(II) Acetate: Synthesis and Binding Properties (Organometallics) Tuesday August 3rd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 84) Organotin-Substituted [13]-Crown-4 Ethers: Ditopic Receptors for Lithium and Cesium Halides† (Organometallics) Tuesday August 3rd 2010 85) Hydrogenolysis versus Methanolysis of First- and Second-Generation Grubbs Catalysts: Rates, Speciation, and Implications for Tandem Catalysis† (Organometallics) Tuesday August 3rd 2010 86) Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1′-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent” Intermediates† (Organometallics) Tuesday August 3rd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 87) Nickel Complexes with Bis(8-quinolyl)silyl Ligands. An Unusual Ni3Si2 Cluster Containing Six-Coordinate Silicon† (Organometallics) Tuesday August 3rd 2010 88) Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study§ (Organometallics) Tuesday August 3rd 2010 89) Chemistry of Butadienesulfinate Salts with (Cp*RhCl2)2 and the Reactivity of Their Derivatives with Tertiary Phosphines (Organometallics) Friday July 30th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 90) Dehydrogenation of Methane by Gas-Phase Th, Th+, and Th2+: Theoretical Insights into Actinide Chemistry (Organometallics) Friday July 30th 2010 91) Synthesis and Structure of a Heptacoordinate Trichlorostannane Bearing a Triarylmethyl-Type Tetradentate Ligand† (Organometallics) Friday July 30th 2010 92) Versatile Chemistry of Butadienesulfinate Salts with (Cp*RuCl)4: Tetrameric, Allylsulfene, and Ion-Pair Ruthenium Compounds (Organometallics) Friday July 30th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 93) Synthesis of Isonitrile, Iminoacyl, and Aminocarbene Tp′Pt Complexes† (Organometallics) Thursday July 29th 2010 94) Mechanisms of the CO2 Insertion into (PCP) Palladium Allyl and Methyl σ-Bonds. A Kinetic and Computational Study (Organometallics) Thursday July 29th 2010 95) Thermal Rearrangement of Osmabenzenes to Osmium Cyclopentadienyl Complexes† (Organometallics) Thursday July 29th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 96) Expeditious Synthesis of [Au(NHC)(L)]+ (NHC = N-Heterocyclic Carbene L = Phosphine or NHC) Complexes† (Organometallics) Thursday July 29th 2010 97) Novel Synthesis of Chiral 1,3-Diphosphines via Palladium Template Promoted Hydrophosphination and Functional Group Transformation Reactions (Organometallics) Thursday July 29th 2010 98) Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes† (Organometallics) Thursday July 29th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote View: prev | next

Search ChemFeeds: Order By: Time Recent Comments: Mitch on 5′-Bis-conjugation of Oligonucleo ... anand on 5′-Bis-conjugation of Oligonucleo ... Rosi on Bridging-ligand-substitution strate ... Cai Kuiyu on Recrystallization induced in situ n ... Chem News Feed: - My E. coli brother's keeper The Curious Wavefunction - When Science Went International Chemical & Engineering News: Latest News - Social Media: An introduction ASSETT - EuCheMS 2010: Mass spec – a vital tool Chemistry World blog - BREAKING: Unemployment at 9.6%, up 0.1% from July Chemjobber - Metformin Against Cancer? In the Pipeline - First Friday: Your Dye Is Bugged—The Process and Ingredients of Dye Periodic Tabloid - 09/01/10 PHD comic: 'You autumn leave' Piled Higher and Deeper RSS Gradfeed - Fragrance Overload? C&ENtral Science - 2010 nobel predictions Everyday Scientist - EuCheMS - Colloids and culture The Sceptical Chymist - Nanopore-Based Screening Chemical & Engineering News: Latest News - Crew Reported Safe In Gulf Oil Platform Fire Chemical & Engineering News: Latest News - Stimulating quasi-erotic excitement through organic structure determination The Curious Wavefunction - Industrial Gas Companies Face Brazilian Fine Muito Grande C&ENtral Science Powered by Feed Informer

Mitch Andre Garcia's Chem Feeds 2008-present

Some images have been reproduced by permission of The Royal Society of Chemistry. (RSC' RSS Policy)
Other images have been reproduced with permission of the American Chemical Society. (ACS' RSS Policy)
Few images have been reproduced with pending permission of Wiley-VCH. ()