1) DNA Ends: Just the Beginning (Nobel Lecture) (Angewandte Chemie International Edition) Friday September 3rd 2010 2) CF Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity (Angewandte Chemie International Edition) Friday September 3rd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 3) Cross‐Coupling in a Flow Microreactor: Space Integration of Lithiation and Murahashi Coupling (Angewandte Chemie International Edition) Friday September 3rd 2010 4) [4+2] Cycloaddition Reaction of Cyclic Alkyne—{Co2(CO)6} Complexes with Dienes (Angewandte Chemie International Edition) Friday September 3rd 2010 5) Flexibility in a Metal–Organic Framework Material Controlled by Weak Dispersion Forces: The Bistability of MIL‐53(Al) (Angewandte Chemie International Edition) Friday September 3rd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 6) Selective Modulation of DNA Polymerase Activity by Fixed‐Conformation Nucleoside Analogues (Angewandte Chemie International Edition) Thursday September 2nd 2010 7) Entropy‐Controlled Catalytic Asymmetric 1,4‐Type Friedel–Crafts Reaction of Phenols Using Conformationally Flexible Guanidine/Bisthiourea Organocatalyst (Angewandte Chemie International Edition) Thursday September 2nd 2010 8) Total Chemical Synthesis of Di‐ubiquitin Chains (Angewandte Chemie International Edition) Thursday September 2nd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 9) Azidohomoalanine: A Conformationally Sensitive IR Probe of Protein Folding, Protein Structure, and Electrostatics (Angewandte Chemie International Edition) Thursday September 2nd 2010 10) Dichlorocyclodibismadiazane (Angewandte Chemie International Edition) Thursday September 2nd 2010 11) Competition between Orbitals and Stress in Mechanochemistry (Angewandte Chemie International Edition) Thursday September 2nd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 12) [Fe]‐Hydrogenase Models Featuring Acylmethylpyridinyl Ligands (Angewandte Chemie International Edition) Thursday September 2nd 2010 13) Efficient Organic‐Dye‐Sensitized Solar Cells Based on an Iodine‐Free Electrolyte (Angewandte Chemie International Edition) Thursday September 2nd 2010 14) The Bicorannulenyl Dianion: A Charged Overcrowded Ethylene (Angewandte Chemie International Edition) Thursday September 2nd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 15) Pharmaceutical Nano‐Cocrystals: Sonochemical Synthesis by Solvent Selection and Use of a Surfactant (Angewandte Chemie International Edition) Thursday September 2nd 2010 16) An Octanuclear [CrIII4DyIII4] 3d–4f Single‐Molecule Magnet (Angewandte Chemie International Edition) Thursday September 2nd 2010 17) Surface‐Tension‐Induced Synthesis of Complex Particles Using Confined Polymeric Fluids (Angewandte Chemie International Edition) Thursday September 2nd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 18) Fluorous Biphase Synthesis of a Poly(p‐phenyleneethynylene) and its Fluorescent Aqueous Fluorous‐Phase Emulsion (Angewandte Chemie International Edition) Thursday September 2nd 2010 19) A Fluorescent Rosamine Compound Selectively Stains Pluripotent Stem Cells (Angewandte Chemie International Edition) Thursday September 2nd 2010 20) Ion Dynamics in Confined Spaces: Sodium Ion Mobility in Icosahedral Container Molecules (Angewandte Chemie International Edition) Wednesday September 1st 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 21) Interaction of Epothilone B (Patupilone) with Microtubules, As Detected by Two‐Dimensional Solid‐State NMR Spectroscopy (Angewandte Chemie International Edition) Tuesday August 31st 2010 22) A Versatile Catalyst for Reductive Amination by Transfer Hydrogenation (Angewandte Chemie International Edition) Tuesday August 31st 2010 23) Efficient Access to Nonhydrolyzable Initiator tRNA Based on the Synthesis of 3′‐Azido‐3′‐Deoxyadenosine RNA (Angewandte Chemie International Edition) Tuesday August 31st 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 24) Total Synthesis of the Marine Antibiotic Pestalone and its Surprisingly Facile Conversion into Pestalalactone and Pestalachloride A (Angewandte Chemie International Edition) Tuesday August 31st 2010 25) Direct Evidence of a Surface Quenching Effect on Size‐Dependent Luminescence of Upconversion Nanoparticles (Angewandte Chemie International Edition) Tuesday August 31st 2010 26) Catalytic Asymmetric Direct Henry Reaction of Ynals: Short Syntheses of (2S,3R)‐(+)‐Xestoaminol C and (−)‐Codonopsinines (Angewandte Chemie International Edition) Tuesday August 31st 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 27) A Bimetallic Titanium Catalyst for the Enantioselective Cyanation of Aldehydes Based on Cooperative Catalysis (Angewandte Chemie International Edition) Tuesday August 31st 2010 28) Facile Synthesis of Copper(II)‐Immobilized Magnetic Mesoporous Silica Microspheres for Selective Enrichment of Peptides for Mass Spectrometry Analysis (Angewandte Chemie International Edition) Monday August 30th 2010 29) A Square‐Planar Ruthenium(II) Complex with a Low‐Spin Configuration (Angewandte Chemie International Edition) Monday August 30th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 30) Template‐Directed Syntheses of Rigid Oligorotaxanes under Thermodynamic Control (Angewandte Chemie International Edition) Monday August 30th 2010 31) Organic Sol–Gel Synthesis: Solution‐Processable Microporous Organic Networks (Angewandte Chemie International Edition) Monday August 30th 2010 32) Scanning Imaging of Magnetic Nanoparticles for Quantitative Molecular Imaging (Angewandte Chemie International Edition) Monday August 30th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 33) A Quantum‐Dot‐Based Molecular Ruler for Multiplexed Optical Analysis (Angewandte Chemie International Edition) Monday August 30th 2010 34) Catalytic Hydrogenation of Norbornadiene by a Rhodium Complex in a Self‐Folding Cavitand (Angewandte Chemie International Edition) Monday August 30th 2010 35) Light‐Induced Control of Protein Translocation by the SecYEG Complex (Angewandte Chemie International Edition) Friday August 27th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 36) Disilanyl Double‐Pillared Bisanthracene: A Bipolar Carrier Transport Material for Organic Light‐Emitting Diode Devices (Angewandte Chemie International Edition) Friday August 27th 2010 37) Using Pressure to Provoke the Structural Transition of Metal–Organic Frameworks (Angewandte Chemie International Edition) Friday August 27th 2010 38) Fluorine‐Enabled Cationic Gold Catalysis: Functionalized Hydration of Alkynes (Angewandte Chemie International Edition) Friday August 27th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 39) Tertiary Aminourea‐Catalyzed Enantioselective Iodolactonization (Angewandte Chemie International Edition) Friday August 27th 2010 40) A Mononuclear Dysprosium Complex Featuring Single‐Molecule‐Magnet Behavior (Angewandte Chemie International Edition) Friday August 27th 2010 41) Putting a Positive Spin on Molecular Bridges (Angewandte Chemie International Edition) Friday August 27th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 42) Trapping Unstable Benzoquinone Analogues by Coordination to a [(η5‐C5Me5)Ir] Fragment and the Anticancer Activity of the Resulting Complexes (Angewandte Chemie International Edition) Friday August 27th 2010 43) Electroactive Organic Molecules Immobilized onto Solid Nanoparticles as a Cathode Material for Lithium‐Ion Batteries (Angewandte Chemie International Edition) Friday August 27th 2010 44) Addressing Protein–Protein Interactions with Small Molecules: A Pro‐Pro Dipeptide Mimic with a PPII Helix Conformation as a Module for the Synthesis of PRD‐Binding Ligands (Angewandte Chemie International Edition) Friday August 27th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 45) Ramón Martínez‐Máñez (Angewandte Chemie International Edition) Thursday August 26th 2010 46) Photochemical Incorporation of Diphosphorus Units into Organic Molecules (Angewandte Chemie International Edition) Thursday August 26th 2010 47) Catalyst‐Controlled Wacker‐Type Oxidation of Protected Allylic Amines (Angewandte Chemie International Edition) Thursday August 26th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 48) Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene–Rhodium Complexes (Angewandte Chemie International Edition) Thursday August 26th 2010 49) Dynamic Peptides as Biomimetic Carbohydrate Receptors (Angewandte Chemie International Edition) Thursday August 26th 2010 50) Glycosidic Prodrugs of Highly Potent Bifunctional Duocarmycin Derivatives for Selective Treatment of Cancer (Angewandte Chemie International Edition) Thursday August 26th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 51) Photoswitchable Nanoassemblies by Electrostatic Self‐Assembly (Angewandte Chemie International Edition) Thursday August 26th 2010 52) An Organocatalytic, δ‐Regioselective, and Highly Enantioselective Nucleophilic Substitution of Cyclic Morita–Baylis–Hillman Alcohols with Indoles (Angewandte Chemie International Edition) Thursday August 26th 2010 53) Ligand‐Clustered “Patchy” Nanoparticles for Modulated Cellular Uptake and In Vivo Tumor Targeting (Angewandte Chemie International Edition) Wednesday August 25th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 54) High‐Density Energetic Mono‐ or Bis(Oxy)‐5‐Nitroiminotetrazoles (Angewandte Chemie International Edition) Wednesday August 25th 2010 55) Palladium‐Catalyzed Carbonylative CH Activation of Heteroarenes (Angewandte Chemie International Edition) Wednesday August 25th 2010 56) The Third Hydrogenase: A Ferracyclic Carbamoyl with Close Structural Analogy to the Active Site of Hmd (Angewandte Chemie International Edition) Wednesday August 25th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 57) Intermolecular Addition of Glycosyl Halides to Alkenes Mediated by Visible Light (Angewandte Chemie International Edition) Wednesday August 25th 2010 58) Fluorescent Quantum Dots as Artificial Antennas for Enhanced Light Harvesting and Energy Transfer to Photosynthetic Reaction Centers (Angewandte Chemie International Edition) Wednesday August 25th 2010 59) Hybrid Uranium‐Oxalate Fullerene Topology Cage Clusters (Angewandte Chemie International Edition) Wednesday August 25th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 60) Well‐Defined Cationic Methallyl α‐Keto‐β‐Diimine Complexes of Nickel (Angewandte Chemie International Edition) Wednesday August 25th 2010 61) A Biologically Inspired Organometallic Fuel Cell (OMFC) That Converts Renewable Alcohols into Energy and Chemicals (Angewandte Chemie International Edition) Wednesday August 25th 2010 62) Circularly Polarized Luminescent CdS Quantum Dots Prepared in a Protein Nanocage (Angewandte Chemie International Edition) Wednesday August 25th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 63) Modern Molecular Photochemistry of Organic Molecules By Nicholas J. Turro, V. Ramamurthy and Juan C. Scaiano. (Angewandte Chemie International Edition) Tuesday August 24th 2010 64) Controlled Delivery Using Oligonucleotide‐Capped Mesoporous Silica Nanoparticles (Angewandte Chemie International Edition) Tuesday August 24th 2010 65) Rhodium(II)‐Catalyzed One‐Pot Four‐Component Synthesis of Functionalized Polyether Macrocycles at High Concentration (Angewandte Chemie International Edition) Tuesday August 24th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 66) Synthesis, Isolation, and Characterization of 1,1‐diGrignard and 1,1‐Dizincio Silanes (Angewandte Chemie International Edition) Tuesday August 24th 2010 67) Cellular Integration of an Enzyme‐Loaded Polymersome Nanoreactor (Angewandte Chemie International Edition) Tuesday August 24th 2010 68) Cation‐Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis (Angewandte Chemie International Edition) Monday August 23rd 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 2 Up Votes 69) Unprecedented Molecular Architectures by the Controlled Self‐Assembly of a β Peptide Foldamer (Angewandte Chemie International Edition) Monday August 23rd 2010 70) Design of Living Ring‐Opening Alkyne Metathesis (Angewandte Chemie International Edition) Monday August 23rd 2010 71) Theoretical Messenger Spectroscopy of Microsolvated Hydronium and Zundel Cations (Angewandte Chemie International Edition) Monday August 23rd 2010 0 comments, related, 2 Up Votes 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 72) Direct Alkynylation of Thiophenes: Cooperative Activation of TIPS–EBX with Gold and Brønsted Acids (Angewandte Chemie International Edition) Friday August 20th 2010 73) Integration of a Fluorescent Molecular Biosensor into Self‐Assembled Protein Nanowires: A Large Sensitivity Enhancement (Angewandte Chemie International Edition) Friday August 20th 2010 74) Oriented Nanoscale Films of Metal–Organic Frameworks By Room‐Temperature Gel‐Layer Synthesis (Angewandte Chemie International Edition) Friday August 20th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 75) Selective Ultrasonic Cavitation on Patterned Hydrophobic Surfaces (Angewandte Chemie International Edition) Thursday August 19th 2010 76) An Integrated Microreactor System for Self‐Optimization of a Heck Reaction: From Micro‐ to Mesoscale Flow Systems (Angewandte Chemie International Edition) Thursday August 19th 2010 77) Aldehyde Umpolung by N‐Heterocyclic Carbenes: NMR Characterization of the Breslow Intermediate in its Keto Form, and a Spiro‐Dioxolane as the Resting State of the Catalytic System (Angewandte Chemie International Edition) Thursday August 19th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 78) Dynamic Nuclear Polarization of Deuterated Proteins (Angewandte Chemie International Edition) Thursday August 19th 2010 79) Isolation and Characterization of the Triradical 1,3,5‐Trimethylenebenzene (Angewandte Chemie International Edition) Thursday August 19th 2010 80) Palladium‐Catalyzed β Arylation of Carboxylic Esters (Angewandte Chemie International Edition) Thursday August 19th 2010 0 comments, related, 2 Up Votes 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 81) Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions (Angewandte Chemie International Edition) Thursday August 19th 2010 82) Coordination and Dehydrogenation of Amine–Boranes at Metal Centers (Angewandte Chemie International Edition) Wednesday August 18th 2010 83) Uniform Hollow Carbon Shells: Nanostructured Graphitic Supports for Improved Oxygen‐Reduction Catalysis (Angewandte Chemie International Edition) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 84) Polyfluorophores on a DNA Backbone: Sensors of Small Molecules in the Vapor Phase (Angewandte Chemie International Edition) Wednesday August 18th 2010 85) Enantioselective Addition of Boronates to Chromene Acetals Catalyzed by a Chiral Brønsted Acid/Lewis Acid System (Angewandte Chemie International Edition) Wednesday August 18th 2010 86) Structural Characterization of a Microperoxidase Inside a Metal‐Directed Protein Cage (Angewandte Chemie International Edition) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 87) The Beginnings of N‐Heterocyclic Carbenes (Angewandte Chemie International Edition) Wednesday August 18th 2010 88) Synthesis of 5‐Substituted 1H‐Tetrazoles from Nitriles and Hydrazoic Acid by Using a Safe and Scalable High‐Temperature Microreactor Approach (Angewandte Chemie International Edition) Wednesday August 18th 2010 89) Complete Regio‐ and Stereoselective Construction of Highly Substituted Silyl Enol Ethers by Three‐Component Coupling (Angewandte Chemie International Edition) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 90) Morphosynthesis of Nanostructured Gold Crystals by Utilizing Interstices in Periodically Arranged Silica Nanoparticles as a Flexible Reaction Field (Angewandte Chemie International Edition) Wednesday August 18th 2010 91) Monooxygenase‐Like Reactivity of an Unprecedented Heterobimetallic {FeO2Ni} Moiety (Angewandte Chemie International Edition) Wednesday August 18th 2010 92) In Vivo Synthesis of Diverse Metal Nanoparticles by Recombinant Escherichia coli (Angewandte Chemie International Edition) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 93) Semiconductor Gas Sensors: Dry Synthesis and Application (Angewandte Chemie International Edition) Wednesday August 18th 2010 94) Efficient Silver‐Catalyzed Regio‐ and Stereospecific Aziridination of Dienes (Angewandte Chemie International Edition) Wednesday August 18th 2010 95) Elementary Steps in Gold Catalysis: The Significance of gem‐Diauration (Angewandte Chemie International Edition) Wednesday August 18th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 0 comments, related, 1 Up Vote 96) Enantiodifferentiating endo‐Selective Oxylactonization of ortho‐Alk‐1‐enylbenzoate with a Lactate‐Derived Aryl‐λ3‐Iodane (Angewandte Chemie International Edition) Wednesday August 18th 2010 97) A Polymer‐Supported Chiral Dirhodium(II) Complex: Highly Durable and Recyclable Catalyst for Asymmetric Intramolecular CH Insertion Reactions (Angewandte Chemie International Edition) Wednesday August 18th 2010 98) The Measure of All Rings—N‐Heterocyclic Carbenes (Angewandte Chemie International Edition) Tuesday August 17th 2010 0 comments, related, 1 Up Vote 0 comments, related, 1 Up 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